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  • 30725-00-9,  2,3-O-异亚丙基-D-核糖酸-1,4-内酯, CAS: 30725-00-9
30725-00-9,  2,3-O-异亚丙基-D-核糖酸-1,4-内酯, CAS: 30725-00-9

30725-00-9, 2,3-O-异亚丙基-D-核糖酸-1,4-内酯, CAS: 30725-00-9

30725-00-9, 2,3-O-Isopropylidene-D-ribonic gamma-lactone ,
2,3-O-异亚丙基-D-核糖酸-1,4-内酯,
CAS: 30725-00-9
C8H12O5 / 188.18
MFCD00080793

2,3-O-异亚丙基-D-核糖酸-1,4-内酯,  2,3-O-Isopropylidene-D-ribonic acid-1,4-lactone

2,3-O-Isopropylidene-D-ribonic acid-1,4-lactone is an organic compound that belongs to the class of lactones. It is a chiral molecule with two asymmetric carbons and four stereogenic atoms. This compound can be used for the synthesis of optically active compounds. It is also a precursor for the synthesis of morpholines and phosphonates. 2,3-O-Isopropylidene-D-ribonic acid-1,4-lactone can be synthesized by reacting an enolate with an aldehyde in the presence of a base and acid catalyst. The acid catalyst causes elimination of water from the enolate to produce the desired product.

CAS Number30725-00-9
Product Name(3aR,6R,6aR)-6-(hydroxymethyl)-2,2-dimethyldihydrofuro[3,4-d][1,3]dioxol-4(3aH)-one
IUPAC Name(3aR,6R,6aR)-6-(hydroxymethyl)-2,2-dimethyl-6,6a-dihydro-3aH-furo[3,4-d][1,3]dioxol-4-one
Molecular FormulaC8H12O5
Molecular Weight188.18 g/mol
InChIInChI=1S/C8H12O5/c1-8(2)12-5-4(3-9)11-7(10)6(5)13-8/h4-6,9H,3H2,1-2H3/t4-,5-,6-/m1/s1
InChI KeyNHHKFJCWLPPNCN-HSUXUTPPSA-N
SMILESCC1(OC2C(OC(=O)C2O1)CO)C
Canonical SMILESCC1(OC2C(OC(=O)C2O1)CO)C
Isomeric SMILESCC1(O[C@@H]2[C@H](OC(=O)[C@@H]2O1)CO)C
CAS No: 30725-00-9 Synonyms: 2,3-O-Isopropylidene-D-ribonic acid y lactoneD-Ribonolactone monoacetonide2,3-O-Isopropylidene-D-ribonolactone MDL No: MFCD00080793 Chemical Formula: C8H12O5 Molecular Weight: 188.18
References: 1. Shiozaki M, Carbohydr. Res. 2002, Vol337, No21, p2077-2088

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