53008-63-2 ,甲基-a-2,3,4,6-O-四苄基-D-半乳糖苷,
Methyl 2,3,4,6-tetra-O-benzyl-a-D-galactopyranoside,
CAS:53008-63-2
C35H38O6 / 554.67
MFCD09756157
甲基-a-2,3,4,6-O-四苄基-D-半乳糖苷
Methyl 2,3,4,6-tetra-O-benzyl-α-D-galactopyranoside (MBGT) is a pharmaceutical that belongs to the class of aziridines. It has shown high light emission properties at temperatures between 25 and 50 °C. MBGT has been used as a shift reagent for the analysis of carbohydrates and glycols. The spectral shift exhibited by MBGT is due to the resonance stabilization of the molecule's excited state. This effect is increased by hydrogen peroxide, which acts as an oxidant and stabilizes the excited state via electron transfer. A bathochromic shift was observed in aqueous solutions at pH 4.5 when methyl 2,3,4,6-tetra-O-benzyl-α-D-galactopyranoside was combined with potassium hydroxide or sodium hydroxide as a base.
CAS Number | 53008-63-2 |
Product Name | (2R,3S,4S,5R,6S)-3,4,5-Tris(benzyloxy)-2-((benzyloxy)methyl)-6-methoxytetrahydro-2H-pyran |
IUPAC Name | 2-methoxy-3,4,5-tris(phenylmethoxy)-6-(phenylmethoxymethyl)oxane |
Molecular Formula | C35H38O6 |
Molecular Weight | 554.67 g/mol |
InChI | InChI=1S/C35H38O6/c1-36-35-34(40-25-30-20-12-5-13-21-30)33(39-24-29-18-10-4-11-19-29)32(38-23-28-16-8-3-9-17-28)31(41-35)26-37-22-27-14-6-2-7-15-27/h2-21,31-35H,22-26H2,1H3 |
InChI Key | IXEBJCKOMVGYKP-NVCPMKERSA-N |
SMILES | COC1C(C(C(C(O1)COCC2=CC=CC=C2)OCC3=CC=CC=C3)OCC4=CC=CC=C4)OCC5=CC=CC=C5 |
Synonyms | Methyl 2,3,4,6-Tetrakis-O-(phenylmethyl)-α-D-galactopyranoside; |
Canonical SMILES | COC1C(C(C(C(O1)COCC2=CC=CC=C2)OCC3=CC=CC=C3)OCC4=CC=CC=C4)OCC5=CC=CC=C5 |
Isomeric SMILES | CO[C@@H]1[C@@H]([C@H]([C@H]([C@H](O1)COCC2=CC=CC=C2)OCC3=CC=CC=C3)OCC4=CC=CC=C4)OCC5=CC=CC=C5 |
CAS No: 53008-63-2 MDL No: MFCD09756157 Chemical Formula: C35H38O6 Molecular Weight: 554.67 |
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