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  • 89-65-6, D-赤藻糖酸, D-Isoascorbic acid, CAS:89-65-6
89-65-6, D-赤藻糖酸, D-Isoascorbic acid, CAS:89-65-6

89-65-6, D-赤藻糖酸, D-Isoascorbic acid, CAS:89-65-6

89-65-6, D-赤藻糖酸,
D-Isoascorbic acid,
CAS:89-65-6
C6H8O6 / 176.124
MFCD00005378

D-Isoascorbic acid

D-赤藻糖酸

D-Isoascorbic acid is a sodium salt of ascorbic acid. It is used for the prevention and treatment of scurvy, which is caused by vitamin C deficiency. D-Isoascorbic acid functions as an electron donor in biochemical reactions and has been shown to have physiological effects. Ascorbic acid (vitamin C) is a water-soluble antioxidant that can react with hydrogen fluoride in vitro to form free radicals that may cause damage to cells. In addition, D-Isoascorbic acid can be used as a model system for the study of ascorbic acid and p-hydroxybenzoic acid. The analytical method for determining these compounds involves electrochemical impedance spectroscopy.

Title: Isoascorbic Acid

CAS Registry Number: 89-65-6

CAS Name: D-erythro-Hex-2-enonic acid g-lactone

Additional Names: D-araboascorbic acid; erythorbic acid; isovitamin C; saccharosonic acid; glucosaccharonic acid; D-erythro-3-ketohexonic acid lactone; D-erythro-3-oxohexonic acid lactone; erycorbin

Trademarks: Mercate "5"; Neo-Cebicure

Molecular Formula: C6H8O6

Molecular Weight: 176.12

Percent Composition: C 40.92%, H 4.58%, O 54.51%

Literature References: Epimer of L-ascorbic acid. Has one-twentieth of the vitamin C activity of L-ascorbic acid. Prepd by treating methyl 2-keto-D-gluconate with sodium methoxide: Maurer, Schiedt, Ber. 66, 1054 (1933); 67, 1239 (1934); Ohle et al., ibid. 67, 324 (1934); Baird et al., J. Chem. Soc. 1934, 63; Reichstein et al., Helv. Chim. Acta 17, 516 (1934). Synthesis from sucrose: Heimann, Reiff, Pharm. Zentralhalle 93, 97 (1954). Production by Penicillium spp: Takahashi et al., Nature 188, 411 (1960); US 3052609 (1962 to Sankyo); Bull. Agric. Chem. Soc. Jpn. 24, 533 (1960), C.A. 55, 1788 (1961). Conformation: Matsui et al., Agric. Biol. Chem. 27, 185 (1963).

Properties: Shiny granular crystals from water or dioxane. Dec 174°. [a]D16.5 -17° (c = 1.8 in 0.01N HCl); [a]D20 -16.6° (H2O). Soluble in water, alc, pyridine. Moderately sol in acetone. Slightly sol in glycerol.

Optical Rotation: [a]D16.5 -17° (c = 1.8 in 0.01N HCl); [a]D20 -16.6° (H2O)

 

Derivative Type: Sodium salt

Additional Names: Sodium erythorbate

Trademarks: Mercate "20"; Neo-Cebitate

Properties: Crystals, sol in water. pH of aq solns of the sodium salt between 5 and 6. A 10% soln, made from commercial grade, may have a pH of 7.2 to 7.9. The free acid is more sol in water (40 g/100 ml H2O) than the sodium salt (16 g/100 ml H2O).

 Use: Antioxidant and antimicrobial agent for foods: Kadin, Osadca, J. Agric. Food Chem. 7, 358 (1959).

CAS Number89-65-6
Product NameErythorbic acid
IUPAC Name(2R)-2-[(1R)-1,2-dihydroxyethyl]-3,4-dihydroxy-2H-furan-5-one
Molecular FormulaC6H8O6
Molecular Weight176.124
InChIInChI=1S/C6H8O6/c7-1-2(8)5-3(9)4(10)6(11)12-5/h2,5,7-10H,1H2/t2-,5-/m1/s1
InChI KeyCIWBSHSKHKDKBQ-DUZGATOHSA-N
SMILESC(C(C1C(=C(C(=O)O1)O)O)O)O
SynonymsAraboascorbic Acid; Araboascorbic Acid, D-; D-(-)-Isoascorbic Acid; D-Araboascorbic Acid; D-Erythorbic Acid; D-Isoascorbic Acid; D-arabino-Ascorbic Acid; E 315; Erycorbin; Glucosaccharonic Acid; Isoascorbic Acid; Isovitamin C; Mercate 5; NSC 8117; Ne
CAS No: 89-65-6 Synonyms: D-Erythorbic acid MDL No: MFCD00005378 Chemical Formula: C6H8O6 Molecular Weight: 176.124

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