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4196-35-4 , Tetra-O-benzyl-a-D-glucopyranosyl bromide ,CAS: 4196-35-4

4196-35-4 , Tetra-O-benzyl-a-D-glucopyranosyl bromide ,
CAS: 4196-35-4
C34H35BrO5 / 603.54

Tetra-O-benzyl-a-D-glucopyranosyl bromide

溴代四苄基-a-D-吡喃葡萄糖,

2,3,4,6-Tetra-O-benzyl-α-D-glucopyranosyl Bromide is a useful synthetic intermediate. It can be used to prepare glycosyl phenylthiosulfonates (Glyco-PTS), a novel reagents for glycoprotein synthesis. It is also used to synthesize oligosaccharides.

CAS Number4196-35-4
Product Name(2R,3R,4S,5R,6R)-3,4,5-Tris(benzyloxy)-2-bromo-6-(3-phenylpropyl)tetrahydro-2H-pyran
IUPAC Name(2R,3R,4S,5R,6R)-2-bromo-3,4,5-tris(phenylmethoxy)-6-(phenylmethoxymethyl)oxane
Molecular FormulaC34H35BrO5
Molecular Weight603.54 g/mol
InChIInChI=1S/C34H35BrO5/c35-34-33(39-24-29-19-11-4-12-20-29)32(38-23-28-17-9-3-10-18-28)31(37-22-27-15-7-2-8-16-27)30(40-34)25-36-21-26-13-5-1-6-14-26/h1-20,30-34H,21-25H2/t30-,31-,32+,33-,34+/m1/s1
InChI KeyWXYNLXPSTFTJJC-RUOAZZEASA-N
SMILESC1=CC=C(C=C1)COCC2C(C(C(C(O2)Br)OCC3=CC=CC=C3)OCC4=CC=CC=C4)OCC5=CC=CC=C5
Synonyms2,3,4,6-Tetrakis-O-(phenylmethyl)-α-D-glucopyranosyl Bromide, ;2,3,4,6-Tetra-O-benzyl-glucopyranosyl Bromide; α-D-2,3,4,6-Tetra-O-benzyl-glucopyranosyl Bromide; 2,3,4,6-Tetra-O-benzyl-1-bromo-1-deoxy-α-D-glucopyranose; 2,3,4,6-Tetra-O-benzyl-α-D-bro
Canonical SMILESC1=CC=C(C=C1)COCC2C(C(C(C(O2)Br)OCC3=CC=CC=C3)OCC4=CC=CC=C4)OCC5=CC=CC=C5
Isomeric SMILESC1=CC=C(C=C1)COC[C@@H]2[C@H]([C@@H]([C@H]([C@H](O2)Br)OCC3=CC=CC=C3)OCC4=CC=CC=C4)OCC5=CC=CC=C5


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